Development of a sustainable and disposable modified Bi-CdFe2O4 electrode for electrochemical sensing of lead (II) and Acetaminophen drug molecule

Citation

Surendra, B. S. and Swamy, M. Mahadeva and Vergis, Bincy Rose and Bhaskar, M. and Shilpa, C. D. and Khasim, Syed and Chan, Kah Yoong and Murthy, H. C. Ananda (2024) Development of a sustainable and disposable modified Bi-CdFe2O4 electrode for electrochemical sensing of lead (II) and Acetaminophen drug molecule. Scientific Reports, 14 (1). ISSN 2045-2322

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Abstract

The study of research proposes a systematic pattern for optimization and fabrication of a sustainablecost effective electrochemical sensor made by Bi-CdFe2O4 (BCDF) nanoparticle and graphite powder. The structural examinations of synthesized BCDF materials were analyzed by specific spectral techniques viz.; P-XRD, SEM-EDX, TEM, XPS, FT-IR and DRS techniques. The modified sensor electrode offer a significant electrochemical properties that can improve the material selectivity and sensitivity actions measured by Cyclic Voltammetric (CV) and Electrochemical Impedance Spectral (EIS) plots. We demonstrated a developed highly-purity BCDF-graphite paste electrode for sensing actions on Paracetamol and Lead (Pb2+) ions under 0.1 M KCl. The excellent sensing activity towards Lead ions and Paracetamol confirmed by its redox potential peaks at scan rate of 1–5V/s with maximum sensitivity of -0.61V and 0.69V respectively. The excellent photo-dye-degradation action of BCDF (98.2%) than those of host CDF (81.6%) on Rose Bengal (RB) dye was demonstrated. Its kinetic study reveals that this process follows first order kinetics and rate constants of the host (18.1×10−3 min−1) and BCDF (39.2×10−3 min−1) were measured. Thus, the synthesized BCDF electrode provides a new perception for developing specific nano-sensor towards detection of toxic metals.

Item Type: Article
Uncontrolled Keywords: Electrochemical sensor. Nanotechnology
Subjects: T Technology > TP Chemical technology > TP248.13-248.65 Biotechnology
Divisions: Faculty of Engineering (FOE)
Depositing User: Ms Nurul Iqtiani Ahmad
Date Deposited: 03 Dec 2024 02:40
Last Modified: 03 Dec 2024 02:40
URII: http://shdl.mmu.edu.my/id/eprint/13170

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