Citation

Tan, Phei Yi and Tan, Kar Ban and Khaw, Chwin Chieh and Ananda Murthy, H. C. and Balachandran, Ruthramurthy and Chen, Soo Kien and Lee, Oon Jew and Chan, Kah Yoong and Ming, Lu (2024) Substituted Bi3.5Mg1.8Nb2.7O13.8 pyrochlores with transition metals (Zn, Ni and Cd): Doping mechanism, structure and electrical properties. Processing and Application of Ceramics, 18 (3). pp. 281-289. ISSN 1820-6131

Text PAC 65 06.pdf - Published Version Restricted to Repository staff only Download (1MB)

Abstract

The influence of transition metals (Zn, Cd and Ni) on bismuth magnesium niobate (Bi3.5Mg1.8Nb2.7O13.8, BMN) pyrochlores was investigated. Considering the difference in their ionic radii, Cd was postulated to substitute Mg at the eight-fold coordinated A-site whereas Zn and Ni were to replace Mg at the six-fold coordinated B-sites of the host structure. Solubility limits in these substitutional pyrochlore solid solutions were determined to be 0.4, 0.1 and 0.3 for Zn, Ni and Cd, respectively. Upon introducing these divalent cation dopants, notable changes in the lattice parameters and grain sizes were observed with increasing dopant concentration. The high dielectric constants, ε ′ of Zn, Cd and Ni doped BMN pyrochlores were discernible with their bulk values of 195–216, 173–195 and 153–195, respectively. The highest ε ′ of 216 was recorded for the composition with Zn = 0.1 in contrast to the lowest value of 153 found in the composition with Ni = 0.1. Meanwhile, these highly insulating divalent cation doped BMN pyrochlores also exhibit low dielectric losses, tan δ whose values are in the order of 10−3 . The excellent dielectric properties allow these novel pyrochlore phases to be potentially applied for the energy storage applications.

Item Type:	Article
Uncontrolled Keywords:	solid state synthesis, dielectric properties
Subjects:	T Technology > TK Electrical engineering. Electronics Nuclear engineering > TK7800-8360 Electronics > TK7871 Electronics--Materials
Divisions:	Faculty of Engineering (FOE)
Depositing User:	Ms Nurul Iqtiani Ahmad
Date Deposited:	04 Nov 2024 06:22
Last Modified:	04 Nov 2024 06:22
URII:	http://shdl.mmu.edu.my/id/eprint/13098

Downloads

Edit (login required)